Below is a quick WMIC CMD line that will change the site assignment of a client remotely. Bare in mind that account you use must have Administrative access to the machine you are targeting.
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Wmic.exe /node:"TARGET-MACHINE-NAME-HERE" /namespace:\\root\ccm path sms_client CALL SetAssignedSite "P01" /NOINTERACTIVE |
This version will read from a text file the machines that require the Site Code change. Again though, bare in mind that the account running the command must have Administrative access to the machines in question.
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Wmic.exe /node:@Machines.txt /namespace:\\root\ccm path sms_client CALL SetAssignedSite "P01" /NOINTERACTIVE |